Rhodamine analogs for molecular ruler applications
| Autor: | Robert M. Strongin, Meiyan Jiang, Jorge O. Escobedo, Yu Hsuan Chu, Peter S. Steyger |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Fluorophore 010405 organic chemistry Process Chemistry and Technology General Chemical Engineering Biomolecule Cationic polymerization Texas Red Time-dependent density functional theory Conjugated system 010402 general chemistry Photochemistry 01 natural sciences Article 0104 chemical sciences Rhodamine chemistry.chemical_compound chemistry Intramolecular force |
| Zdroj: | Dyes and Pigments. 126:46-53 |
| ISSN: | 0143-7208 |
| DOI: | 10.1016/j.dyepig.2015.11.015 |
| Popis: | A series of geometrically well-defined cationic fluorophores were designed based on molecular mechanics. They contain biaryl linkers to impart rigidity preventing intramolecular folding between a conjugated biomolecule and fluorophore. All probes have absorption and emission maxima within 20 nm from Texas Red, as predicted by TDDFT calculations and validated experimentally. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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