Photoluminescence, optical gain, and lasing threshold in CH3NH3PbI3 methylammonium lead-halide perovskites obtained by ab initio calculations
| Autor: | Claudia Caddeo, Alessio Filippetti, Alessandro Mattoni, Pietro Delugas |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Photoluminescence Ab initio 02 engineering and technology General Chemistry Methylammonium lead halide 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Condensed Matter::Materials Science chemistry.chemical_compound chemistry Ab initio quantum chemistry methods Materials Chemistry Charge carrier Ab initio calculations Band-to-band recombination Charge recombinations Halide perovskitesImportant featuresLasing threshold Recombination rate Strong absorptions Atomic physics 0210 nano-technology Absorption (electromagnetic radiation) Lasing threshold Recombination |
| Zdroj: | JOURNAL OF MATERIALS CHEMISTRY C 5 (2017): 12758–12768. doi:10.1039/c7tc04717g info:cnr-pdr/source/autori:Filippetti, A.; Caddeo, C.; Delugas, P.; Mattoni, A./titolo:Photoluminescence, optical gain, and lasing threshold in CH3NH3PbI3 methylammonium lead-halide perovskites obtained by ab initio calculations/doi:10.1039%2Fc7tc04717g/rivista:JOURNAL OF MATERIALS CHEMISTRY C/anno:2017/pagina_da:12758/pagina_a:12768/intervallo_pagine:12758–12768/volume:5 |
| ISSN: | 2050-7534 2050-7526 |
| DOI: | 10.1039/c7tc04717g |
| Popis: | Using ab initio band energy calculations and van Roosbroeck-Shockley recombination theory, we model transient photoluminescence for lead-iodide CH3NH3PbI3 perovskites. We provide clear evidence that the most important features of the photoluminescence process, i.e. strong absorption, low recombination rates, and long lifetimes, can be all coherently derived from the band-to-band recombination process, and the sometimes invoked contradiction between strong absorption and low recombination rate in a direct band-gap material has no reason to exist; optical gain and charge carrier lasing threshold are also reproduced in satisfactory agreement with the observed values, at least within a significant charge-injection range. Our description provides a solid theoretical assessment to the widespread but debated idea that photoluminescence in these materials is predominantly produced by unbound charge recombination. |
| Databáze: | OpenAIRE |
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