| Popis: |
Herein, a novel poly(2-mercaptobenzothiazole) coated magnetic nanoadsorbent derived from zeolitic-imidazole framework-8 (ZIF-8) was synthesized and then employed for the extraction/preconcentration of trace amounts of palladium and silver in various real matrixes. In this way, magnetite was fabricated first, and then functionalized with tetraethyl orthosilicate. After that, the synthesized magnetite@silica was coated with the ZIF-8 to obtain magnetic ZIF-8. Afterward, the magnetic ZIF-8 was pyrolyzed under the protection of a nitrogen atmosphere to get a magnetic carbon nanoadsorbent. Finally, the magnetic carbon was functionalized with a conductive polymer (poly-2-mercaptobenzothiazole). Fabrication of the nanoadsorbent was affirmed with scanning and transmission electron microscopies, elemental analysis, X-ray diffraction, Fourier transform infrared spectroscopy, and vibrating sample magnetometry. The method is linear from 0.25 to 200 μg L |
