Towards longer-lived metal-to-ligand charge transfer states of iron(ii) complexes: an N-heterocyclic carbene approach

Autor:	Kenneth Wärnmark, André Fleckhaus, Erik Göransson, Pavel Chábera, Alice Corani, Sophie E. Canton, Reiner Lomoth, Villy Sundström, Tobias Harlang, Karina Suárez-Alcántara, Yizhu Liu, Dimali A. Vithanage
Rok vydání:	2013
Předmět:	010405 organic chemistry Chemistry Ligand Stereochemistry Metals and Alloys Charge (physics) General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences 3. Good health Surfaces Coatings and Films Electronic Optical and Magnetic Materials Pincer movement Metal chemistry.chemical_compound Crystallography visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Carbene Order of magnitude
Zdroj:	Chemical Communications
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c3cc43833c
Popis:	A 9 ps (MLCT)-M-3 lifetime was achieved by a Fe-II complex based on C(NHC)boolean AND N(py)boolean AND C(NHC) pincer ligands. This is the longest known so far for any kind of complexes of this abundant metal, and increased by almost two orders of magnitude compared to the reference Fe-II bis-terpyridine complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fdcbbae7eab300feeece3535967ef168 https://doi.org/10.1039/c3cc43833c Zobrazit plný text záznamu