Synthesis, characterization, and assessment of novel sulfonated polynorbornene dicarboximides as adsorbents for the removal of heavy metals from water
| Autor: | Carlos Corona-García, Arlette A. Santiago, Ismeli Alfonso, Mercedes Gabriela Téllez Arias, Joel Vargas, Mohamed Abatal, Isabel Ruiz |
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| Rok vydání: | 2021 |
| Předmět: |
Health
Toxicology and Mutagenesis Metal ions in aqueous solution Inorganic chemistry 010501 environmental sciences Sulfonic acid 01 natural sciences Metal Adsorption Metals Heavy Spectroscopy Fourier Transform Infrared Environmental Chemistry Freundlich equation 0105 earth and related environmental sciences chemistry.chemical_classification Aqueous solution Water General Medicine Polymer Hydrogen-Ion Concentration Pollution Kinetics Polymerization chemistry visual_art visual_art.visual_art_medium Plastics Water Pollutants Chemical Cadmium |
| Zdroj: | Environmental Science and Pollution Research. 28:52014-52031 |
| ISSN: | 1614-7499 0944-1344 |
| DOI: | 10.1007/s11356-021-13757-1 |
| Popis: | The occurrence of heavy metals in the natural aquatic systems arising from anthropogenic sources is an issue of global and environmental concern because of their extremely harmful effects to living beings even in rather low concentrations. The synthesis and ring-opening metathesis polymerization (ROMP) of novel norbornene dicarboximides bearing highly aromatic pendant groups, specifically, N-4-tritylphenyl-norbornene-5,6-dicarboximide (2a) and N-2,4,6-(triphenyl)phenyl-norbornene-5,6-dicarboximide (2b), their hydrogenation and further polymer sulfonation to render them adsorbents for the uptake of heavy metal ions from water is reported in this study. The macromolecules were characterized by means of FT-IR, 1H NMR, and thermal analysis, among others. A thoroughly kinetic and isothermal study of adsorption in single and ternary aqueous solutions of Pb2+, Cd2+, and Ni2+ was performed considering several experimental variables for instance initial metal concentration, contact time and solution pH. In general, the experimental data were adjusted more efficiently to the pseudo-second order kinetic model and to the Freundlich isotherm model, respectively. The maximum removal amounts were found to be 55.7 mg/g for Pb2+, 33.9 mg/g for Cd2+, and 10.2 mg/g for Ni2+ in the sulfonated trityl-bearing polymer 5a while those found for the sulfonated triphenyl-bearing polymer 5b were 31.5 mg/g for Pb2+, 26.6 mg/g for Cd2+, and 7.0 mg/g for Ni2+, respectively. The higher heavy metal removal capacity of polymer 5a was attributed to its also higher degree of sulfonation. The outcomes indicate that these novel sulfonic acid containing polymer-based adsorbents are effective for the uptake of heavy metallic elements from water. |
| Databáze: | OpenAIRE |
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