Autor:	Emily E. Norwine, John J. Kiernicki, Matthias Zeller, Nathaniel K. Szymczak
Rok vydání:	2022
Předmět:	Colloid and Surface Chemistry General Chemistry Ligands Oxidation-Reduction Biochemistry Copper Catalysis Boron Lewis Acids
Zdroj:	Journal of the American Chemical Society. 144:15038-15046
ISSN:	1520-5126 0002-7863
DOI:	10.1021/jacs.2c02937
Popis:	We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of chemical oxidation: hydride transfer to CO
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fd8b889dce5989ffe38695402aa6b414 https://doi.org/10.1021/jacs.2c02937 Zobrazit plný text záznamu