Copper catalyzed atom transfer radical cascade reactions in the presence of free-radical diazo initiators as reducing agents
| Autor: | Carolynne Ricardo, Tomislav Pintauer |
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| Rok vydání: | 2009 |
| Předmět: |
Tris
Reducing agent Atom-transfer radical-polymerization Metals and Alloys General Chemistry Photochemistry Medicinal chemistry Radical cyclization Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Atom Materials Chemistry Ceramics and Composites Copper catalyzed Diazo Amine gas treating |
| Zdroj: | Chemical Communications. :3029 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/b905839g |
| Popis: | Exceptional activity of [Cu(II)(TPMA)Cl][Cl] (TPMA = tris(2-pyridylmethyl)amine) complex in atom transfer radical addition (ATRA) of CCl(4) to 1,6-dienes followed by sequential atom transfer radical cyclization (ATRC) in the presence of free-radical diazo initiators as reducing agents is reported. |
| Databáze: | OpenAIRE |
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