Development of a novel phosphoramidite-selenide ligand for Pd-catalyzed asymmetric allylic substitution
| Autor: | Bin Feng, Pei-Wen Fang, Gui-Man Lan, Li-Yan Peng, Lu-Fang Liang, Ge-Yun You |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Organic & Biomolecular Chemistry. 20:7415-7418 |
| ISSN: | 1477-0539 1477-0520 |
| Popis: | A novel chiral P,Se-heterodonor ligand has been designed and prepared through an efficient and simple operation. This ligand can be successfully applied to Pd-catalyzed asymmetric allylic substitution with C- and N-nucleophiles, producing a diverse range of chiral allylic products in high yields and enantioselectivities (up to 99% yield and 95% ee). |
| Databáze: | OpenAIRE |
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