Structure and Magnetic Properties of the Radical Cation Salt of a TTF-based NiII Complex
| Autor: | Stefan Dolder, Christina Ambrus, Silvio Decurtins, Gaël Labat, Shi-Xia Liu, Antonia Neels |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Salt (chemistry) Crystal structure Condensed Matter Physics Magnetic susceptibility Atomic and Molecular Physics and Optics Magnetic exchange Crystallography Nuclear magnetic resonance Radical ion chemistry Intramolecular force 540 Chemistry 570 Life sciences biology General Materials Science |
| Zdroj: | Liu, Shi-Xia; Ambrus, Christina; Dolder, Stefan; Neels, Antonia; Labat, Gaël; Decurtins, Silvio (2006). Structure and magnetic properties of the radical cation salt of a TTF-based Ni(II) complex. Journal of low temperature physics, 142(3-4), pp. 457-460. Dordrecht: Springer 10.1007/s10909-006-9137-4 |
| DOI: | 10.1007/s10909-006-9137-4 |
| Popis: | Chemical oxidation of a TTF-based NiII complex with I2 produces the corresponding radical cation salt 1, [Ni2Cl2(L)2](I3)2(I5)2(I2)(H2O)2(C4H8O)3, (L=4,5-bis(2-pyridylmethylsulfanyl)-4',5'-ethylenedithiotetrathiafulvalene). The results of magnetic susceptibility measurements show the occurrence of intramolecular magnetic exchange interactions in 1. The lack of close S···S contacts, confirmed by crystal structure analysis, results in an insulating behavior |
| Databáze: | OpenAIRE |
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