Catalyst free, base free microwave irradiated synthesis of aryl nitrites from potassium aryltrifluoroborates and bismuth nitrate

Autor:	Rebecca L. Welch, Mohammad Al-Masum
Jazyk:	angličtina
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Base (chemistry) Chemistry Aryl Potassium Organic Chemistry Inorganic chemistry chemistry.chemical_element Free base Biochemistry Toluene Article Catalysis chemistry.chemical_compound Transition metal Drug Discovery Nitrite
Popis:	A mixture of bismuth nitrate pentahydrate and potassium aryltrifluoroborate in toluene under microwave heating at 120 °C for 20 min provides an interesting and mild reaction protocol for the synthesis of aryl nitrite. The conversion to aryl nitrites from aryltrifluoroborates without transition metal catalyst and base in high yields is remarkable.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fce7a2d26940663e33a23bb4679231b8 https://europepmc.org/articles/PMC4165087/ Zobrazit plný text záznamu