Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(Ii) Complex and Generation of Bioactive Adamanate Amines
| Autor: | Babu Shubha Priya, Prashant Kashinath Metri, Shilpa Eshwar Rao, Suresha Nayakanahundi Deveshegowda, Ganga Periyasamy, Basappa, Peter E. Lobie, Gayathri Virupaiah, Baburajeev Chumadathil Pookunoth, Kashifa Fazl-Ur-Rahman, Rangappa Knchugarakoppal Subbegowda, Vijay Pandey |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
010402 general chemistry
lcsh:Chemical technology 01 natural sciences Catalysis lcsh:Chemistry chemistry.chemical_compound cobalt complex Buchwald–Hartwig reaction lcsh:TP1-1185 Physical and Theoretical Chemistry Benzene adamantanyl-tethered-biphenylamines chemistry.chemical_classification arylamination reactions polymer-supported catalyst 010405 organic chemistry Polymer Divinylbenzene Recyclable catalyst Combinatorial chemistry 0104 chemical sciences chemistry lcsh:QD1-999 Polystyrene Polymer supported |
| Zdroj: | Catalysts, Vol 10, Iss 1315, p 1315 (2020) Catalysts Volume 10 Issue 11 |
| ISSN: | 2073-4344 |
| Popis: | We herein report the preparation and characterization of an inexpensive polymer supported 1,3-bis(benzimidazolyl)benzeneCo(II) complex [PS-Co(BBZN)Cl2] as a catalyst by using the polymer (divinylbenzene cross-linked chloromethylated polystyrene), on which 1,3-bis(benzimidazolyl)benzeneCo(II) complex (PS-Co(BBZN)Cl2) has been immobilized. This catalyst was employed to develop arylamination reaction and robustness of the same reaction was demonstrated by synthesizing various bioactive adamantanyl-tethered-biphenylamines. Our synthetic methodology was much improved than reported methods due to the use of an inexpensive and recyclable catalyst. |
| Databáze: | OpenAIRE |
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