| Autor: |
Muhammad Mufakkar, Islam Ullah Khan, Abdul Waheed, Hoong-Kun Fun, Saeed Ahmad |
| Rok vydání: |
2012 |
| Předmět: |
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| Zdroj: |
Acta Crystallographica Section E: Structure Reports |
| ISSN: |
1600-5368 |
| DOI: |
10.1107/s1600536812043437 |
| Popis: |
The title compound, [Cu(6)I(6)(C(2)H(6)N(2)S)(6)], was obtained from the reaction of copper(I) iodide with N-methyl-thio-urea (Metu) in equimolar amounts in acetonitile. The complex consists of two six-membered trinuclear Cu(3)S(3)I(3) cores that combine through triply bridging Metu, forming a hexa-nuclear core which has -3 symmetry. The Cu(II) atom is coordinated by three S atoms of Metu and one iodide ion in a distorted tetra-hedral geometry. The crystal structure is stabilized by N-H⋯I hydrogen bonds and cuprophilic inter-actions [Cu⋯Cu = 3.0264 (9) Å]. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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