The Origin of Thermochromic Behavior in Distibines: Still an Open Question
| Autor: | Stephan Schulz, Stefan Heimann, Dieter Bläser, Andreas Kuczkowski, Christoph Wölper |
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| Rok vydání: | 2013 |
| Předmět: |
Thermochromism
In situ crystallization Chemistry Fakultät für Chemie » Anorganische Chemie Organic Chemistry Intermolecular force Chemie Solid-state Inorganic Chemistry Bond length Crystallography Phase (matter) ddc:540 Physical and Theoretical Chemistry Distibine -- Laser-Assisted Crystallization -- Intermolecular Interactions -- Thermochromicity |
| Zdroj: | Organometallics. 32:3391-3394 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om4003413 |
| Popis: | A detailed structural investigation of Sb2Et4 using an in situ crystallization technique clearly shows that thermochromic behavior of distibines cannot be solely attributed to the formation of intermolecular Sb···Sb interactions in the solid state. Both the yellow and the red phase of Sb2Et4 showed almost identical bond lengths and angles including rather short intermolecular Sb···Sb bond distances. |
| Databáze: | OpenAIRE |
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