Second-Generation Light-Fueled Supramolecular Pump
| Autor: | Alberto Credi, Martina Canton, Massimo Baroncini, Serena Silvi, Jessica Groppi, Stefano Corra, Lorenzo Casimiro |
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| Přispěvatelé: | Canton, Martina, Groppi, Jessica, Casimiro, Lorenzo, Corra, Stefano, Baroncini, Massimo, Silvi, Serena, Credi, Alberto |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Supramolecular chemistry
Non-equilibrium thermodynamics 010402 general chemistry 01 natural sciences Biochemistry Catalysis supramolecular chemistry Photochromism Colloid and Surface Chemistry rotaxane molecular machine photochemistry 010405 organic chemistry Chemistry business.industry Communication General Chemistry Modular design photochromism Molecular machine 0104 chemical sciences Maxima and minima molecular motor azobenzene Modulation Chemical physics crown ether Dissipative system business |
| Zdroj: | Journal of the American Chemical Society |
| Popis: | We describe the modular design of a pseudorotaxane-based supramolecular pump and its photochemically driven autonomous nonequilibrium operation in a dissipative regime. These properties derive from careful engineering of the energy maxima and minima along the threading coordinate and their light-triggered modulation. Unlike its precursor, this second-generation system is amenable to functionalization for integration into more complex devices. |
| Databáze: | OpenAIRE |
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