Series of Dicyanamide-Interlaced Assembly of Zinc-Schiff-Base Complexes: Crystal Structure and Photophysical and Thermal Studies
| Autor: | Aline Nonat, Monami Maiti, Samiran Mitra, Santarupa Thakurta, Loïc J. Charbonnière, Ray J. Butcher, Dipali Sadhukhan, Syamantak Roy, Guillaume Pilet |
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| Přispěvatelé: | Department of Chemistry, Jadavpur University, Laboratoire des Multimatériaux et Interfaces (LMI), Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Department of Chemistry, Howard University, Howard University, Institut Pluridisciplinaire Hubert Curien (IPHC), Université de Strasbourg (UNISTRA)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2012 |
| Předmět: |
Models
Molecular Nitrogen Stereochemistry chemistry.chemical_element Zinc Crystal structure [CHIM.INOR]Chemical Sciences/Inorganic chemistry Crystallography X-Ray Ligands 010402 general chemistry 01 natural sciences Absorption Inorganic Chemistry chemistry.chemical_compound Organometallic Compounds [CHIM.CRIS]Chemical Sciences/Cristallography [CHIM]Chemical Sciences Physical and Theoretical Chemistry Dicyanamide Schiff Bases Ions Schiff base Molecular Structure 010405 organic chemistry Temperature [CHIM.MATE]Chemical Sciences/Material chemistry Photochemical Processes 0104 chemical sciences Oxygen Crystallography chemistry Cyanamide |
| Zdroj: | Inorganic Chemistry Inorganic Chemistry, American Chemical Society, 2012, 51 (22), pp.12176-12187. ⟨10.1021/ic3012958⟩ |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/ic3012958 |
| Popis: | International audience; Four new dicyanamide (dca) bridged multinuclear ZnII-Schiff-base complexes, {[Zn2L1(μ1,5-dca)dca]·CH3OH}2 (1), [Zn2L2(μ1,5-dca)dca]n (2), [Zn3L32(μ1,5-dca)2]n (3), and [(ZnL4)2Zn(μ1,5-dca)dca]n (4), have been synthesized using four different Schiff bases L1H2 = N,N/-bis(3-methoxysalicylidenimino)-1,3-diaminopentane, L2H2 = N,N′-bis(5-bromo-3-methoxysalicylidenimino)-1,3-diaminopropane, L3H2 = N,N′-bis(5-bromosalicylidenimino)-1,3-diaminopropane, and L4H2 = N,N′-bis(5-chlorosalicylidenimino)-1,3-diaminopropane and NaN(CN)2 in order to extend the metal–ligand assembly. The directional properties of linear end-to-end bridging dca ligands have resulted in different metal ion connectivities leading to unique variety of templates in each of the complexes. All the ligands and complexes have been characterized by microanalytical and spectroscopic techniques. The structures of the complexes have been conclusively determined by single crystal X-ray diffraction studies. Thermogravimetric analyses have been performed to investigate the thermal stability of the metal–organic frameworks. Finally, the photoluminescence properties of the complexes as well as their respective ligands have been investigated with a comparative approach. |
| Databáze: | OpenAIRE |
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