Migration of nanoparticles across a polymer–polymer interface: theory and simulation
| Autor: | Didier R. Long, Nigel Gibbions, Nigel Clarke |
|---|---|
| Přispěvatelé: | Department of Physics and Astronomy [Sheffield], University of Sheffield [Sheffield], Laboratoire Polymères et Matériaux Avancés (LPMA), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2021 |
| Předmět: |
chemistry.chemical_classification
Materials science Capillary action Flow (psychology) Nanoparticle 02 engineering and technology General Chemistry Polymer 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Physics::Fluid Dynamics Condensed Matter::Soft Condensed Matter [CHIM.POLY]Chemical Sciences/Polymers chemistry Chemical physics [PHYS.MECA.MEFL]Physics [physics]/Mechanics [physics]/Fluid mechanics [physics.class-ph] Wetting Polymer blend Dewetting Current (fluid) 0210 nano-technology [PHYS.COND.CM-SCM]Physics [physics]/Condensed Matter [cond-mat]/Soft Condensed Matter [cond-mat.soft] |
| Zdroj: | Soft Matter Soft Matter, Royal Society of Chemistry, 2021, 17 (31), pp.7294-7310. ⟨10.1039/d1sm00671a⟩ |
| ISSN: | 1744-6848 1744-683X |
| DOI: | 10.1039/d1sm00671a |
| Popis: | International audience; We proposed recently a theoretical description for hydrodynamic flows in inhomogeneous liquids in the vicinity of solid interfaces, consistent with current theoretical descriptions of the thermodynamical equilibrium of liquids in the vicinity of solid surfaces and with the Onsager formalism for linear response theory in out-of-equilibrium liquids. We showed that these equations allow for describing diffusio-osmosis along a capillary and also wetting/dewetting dynamics of liquids on a solid substrate. We now apply this physical model to the wetting/dewetting dynamics of nano-particles in polymer blends, showing how they reach equilibrium at the interface between two liquids at rest and how they migrate from the non-preferred polymer to the preferred one under applied flow. |
| Databáze: | OpenAIRE |
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