Palladium-catalyzed hydroesterification of olefins with isosorbide in standard and Br?nsted acidic ionic liquids
| Autor: | Mathias Ibert, André Mortreux, Eric Monflier, Jérôme Boulanger, Thomas Chenal, Mathieu Sauthier, Anne Ponchel, Bastien Léger, Adeline Seingeot, Romain Pruvost |
|---|---|
| Přispěvatelé: | Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, UCCS Équipe Catalyse Supramoléculaire, Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille-Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, Roquette Frères, Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Isosorbide
010405 organic chemistry Chemistry Process Chemistry and Technology chemistry.chemical_element General Chemistry [CHIM.CATA]Chemical Sciences/Catalysis 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Phase (matter) Ionic liquid medicine Organic chemistry [CHIM]Chemical Sciences Triphenylphosphine Selectivity ComputingMilieux_MISCELLANEOUS Palladium medicine.drug |
| Zdroj: | Catalysis Communications Catalysis Communications, Elsevier, 2015, Catalysis Communications, 69, pp.143-146. ⟨10.1016/j.catcom.2015.06.008⟩ Catalysis Communications, 2015, Catalysis Communications, 69, pp.143-146. ⟨10.1016/j.catcom.2015.06.008⟩ |
| ISSN: | 1566-7367 |
| DOI: | 10.1016/j.catcom.2015.06.008⟩ |
| Popis: | The palladium catalyzed hydroesterification of 1-octene with isosorbide was studied in standard and Bronsted acidic ionic liquids as reaction media. High conversions and selectivities towards the targeted isosorbide diesters have been achieved by using a catalytic system composed of Pd(OAc) 2 and trisulfonated triphenylphosphine dissolved in 1-(4-sulfonic acid)-butyl-3-methylimidazolium tosylate. The catalytic phase can be reused several times without any significant decrease in activity and selectivity. |
| Databáze: | OpenAIRE |
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