FeCoNi Ternary Nano-Alloys Embedded in a Nitrogen-Doped Porous Carbon Matrix with Enhanced Electrocatalysis for Stable Lithium–Sulfur Batteries

Autor: Yang Lin, Jianchao Li, Wenju Xie, Zhiyong Ouyang, Jie Zhao, Yanhe Xiao, Shuijin Lei, Baochang Cheng
Rok vydání: 2022
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 14:51001-51009
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.2c15918
Popis: The application of composite materials that combine the advantages of carbonaceous material and metal alloy proves to be a valid method for improving the performance of lithium-sulfur batteries (LSBs). Herein iron-cobalt-nickel (FeCoNi) ternary alloy nanoparticles (FNC) that spread on nitrogen-doped carbon (NC) are obtained by a strategy of low-temperature sol-gel followed by annealing at 800 °C under an argon/hydrogen atmosphere. Benefiting from the synergistic effect of different components of FNC and the conductive network provided by the NC, not only can the "shuttle effect" of lithium polysulfides (LiPS) be suppressed, but also the conversion of LiPS, the diffusion of Li
Databáze: OpenAIRE