Vapor–Liquid Equilibria of Binary Mixtures Containing 1-Butanol and Hydrocarbons at 313.15 K

Autor:	Carmen M. Martin, Rosa M. Villamañán, Ahmed Ait Kaci, Latifa Negadi, Miguel A. Villamañán, Aouicha Belabbaci
Rok vydání:	2011
Předmět:	Activity coefficient chemistry.chemical_compound Heptane UNIQUAC Cyclohexane chemistry Dodecane General Chemical Engineering Azeotrope Non-random two-liquid model Thermodynamics General Chemistry Total pressure
Zdroj:	Journal of Chemical & Engineering Data. 57:114-119
ISSN:	1520-5134 0021-9568
Popis:	Total pressure measurements made at 313.15 K by the static method for five binary mixtures 1-butanol + heptane, 2,2,4-trimethylpentane, dodecane, cyclohexane, and methylbenzene are presented. Data reduction by Barker's method provides correlations for GE, using the four-parameter Margules equation; also the Wilson, nonrandom two-liquid (NRTL), and universal quasichemical activity coefficient (UNIQUAC) models have been used for fitting binary systems. The five investigated mixtures exh ibit a positive deviation from ideality. No azeotrope has been detected for 1-butanol + dodecane, and the other systems show positive azeotropy. Good results a re-obtained in the prediction of total pressure for these systems.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb4ad849b0e2321760f82823046c95e9 https://doi.org/10.1021/je200840e Zobrazit plný text záznamu