Hydrodesulfurization Activity of Zeolite Supported Nickel-and Cobalt Sulfide Catalysts

Autor:	Welters, W.J.J., Koranyi, T.I., de Beer, V.H.J., van Santen, R.A., Guczi, L., Solymosi, F., Tétényi, P.
Přispěvatelé:	Inorganic Materials & Catalysis
Rok vydání:	1993
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Nickel chemistry Sulfide Inorganic chemistry Thiophene Sulfidation chemistry.chemical_element Zeolite Hydrodesulfurization Cobalt sulfide Catalysis
Zdroj:	New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19-24, 1992. Part C, 1931-1934 STARTPAGE=1931;ENDPAGE=1934;TITLE=New Frontiers in Catalysis : Proceedings of the 10th International Congress on Catalysis, Budapest, July 19-24, 1992. Part C
DOI:	10.1016/s0167-2991(08)64193-2
Popis:	Various zeolite (NaY or CaY) supported metal sulfide (Ni or Co) catalysts were prepared (impregnation or ion exchange) and characterized by means of thiophene HDS, 129 Xe NMR and TPS. Especially the acidic zeolites showed a very high initial activity. The observed activity differences are discussed in terms of sulfidation, dispersion, position of the metalsulfide relative to the zeolite pore system and acidity, the latter two being the most important. It is concluded that small Ni and Co sulfide clusters are very efficient thiophene desulfurization catalysts.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb34ae26889d6280602dc2b3f1d870c9 https://doi.org/10.1016/s0167-2991(08)64193-2 Zobrazit plný text záznamu