Silver(I) Coordination Polymer of 2,5-Bis- (4‘,5‘-bis(methylthio)-1‘,3‘-dithiol-2‘-ylidene)- 1,3,4,6-tetrathiapentalene (TTM-TTP) and Its Highly Conductive Iodine Derivative

Autor:	Takayoshi Kuroda-Sowa, Megumu Munakata, Yusaku Suenaga, Hisashi Konaka, Yohji Misaki, Masahiko Maekawa, Jian Chu Zhong
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Coordination polymer Supramolecular chemistry Dithiol chemistry.chemical_element Polymer Iodine Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Physical and Theoretical Chemistry Electrical conductor Derivative (chemistry)
Zdroj:	Inorganic Chemistry. 40:7096-7098
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic010630h
Popis:	The novel silver(I) coordination polymer with 2,5-bis(4‘,5‘-bis(methylthio)-1‘,3‘-dithiol-2‘ylidene)-1,3,4,6-tetrathiapentalene (TTM-TTP), [Ag(TTM-TTP)(CF3SO3)]n (1), which consists of 1-D waving chains, was synthesized and characterized. Polymer 1 can be also regarded as a 3-D supramolecular network formed via many shorter side-by-side and face-to-face S···S contacts. This polymer and its iodine-doped compound 2 behave as semiconductors with σ25°C values of 7.1 × 10-6 and 0.85 S cm-1, respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::faf9af77f28aab0a05bd4b76d2cb9288 https://doi.org/10.1021/ic010630h Zobrazit plný text záznamu