Exo-methylene-BEDT-TTF and alkene-functionalised BEDT-TTF derivatives: synthesis and radical cation salts

Autor: Jordan R. Lopez, Simon J. Coles, Matteo Zecchini, Lee Martin, Scott W. Allen, Hiroki Akutsu, Claire Wilson, John D. Wallis
Jazyk: angličtina
Rok vydání: 2015
Předmět:
ISSN: 2046-2069
Popis: Hydroxymethyl-BEDT-TTF is converted by tosylation and elimination into exo-methylene-BEDT-TTF whose exocyclic double bond leads to a small increase in the oxidation potential, and from which radical cation salts with perchlorate and triiodide have been prepared, the latter showing semiconductor properties. Allyloxymethyl- and allylthiomethyl-BEDT-TTF, the first BEDT-TTF derivatives with an alkene in the side chain, have been prepared, along with a 1 : 2 radical cation perchlorate salt of the former, an insulator which contains a donor dication.
Databáze: OpenAIRE