Graphene-supported Pt and PtPd nanorods with enhanced electrocatalytic performance for the oxygen reduction reaction
Autor: | Tsan-Yao Chen, Chien Te Hsieh, Yi Chia Tseng, Shu Ru Chung, Cheng En Lee, Yu Ting Liang, Hong Shuo Chen, Kuan Wen Wang, Chen Wei Liu |
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Rok vydání: | 2014 |
Předmět: | |
Zdroj: | Chem. Commun.. 50:11165-11168 |
ISSN: | 1364-548X 1359-7345 |
Popis: | The combinational modification of the morphology, alloying, and support for Pt catalysts has been optimized towards the oxygen reduction reaction. Graphene-supported PtPd nanorods have lower unfilled Pt d-states than carbon-supported Pt nanoparticles (Pt/C) and their specific and mass activities after the accelerated durability test are about 6.5 and 2.7 times higher than those of Pt/C, attributed to the synergistic electronic modification effect and graphene-metal interaction. |
Databáze: | OpenAIRE |
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