Carbon-Acylation of Benzoic Anhydride Derivatives by Electroreduction

Autor:	Masato Matsunami, Shun Mizoguchi, Hirofumi Maekawa, Ikuzo Nishiguchi
Rok vydání:	2007
Předmět:	Acylation chemistry.chemical_compound Thesaurus (information retrieval) chemistry chemistry.chemical_element Organic chemistry Carbon Benzoic anhydride
Zdroj:	ECS Transactions. 2:29-32
ISSN:	1938-6737 1938-5862
DOI:	10.1149/1.2409002
Popis:	Electroreduction of benzoic anhydride derivatives in the presence of aliphatic acid anhydrides gave the corresponding C- and O-diacylated products or 1,2-diacetoxy olefins depending upon the reaction conditions. Particularly, nucleophilic acylation of carbonyl carbon atoms may be an interesting reaction in organic synthesis. C- and O-diacylated products are useful as starting materials of sympathomimetic drugs such as epinephrine and ephedrine derivatives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa8a328466cfae2b5e30819327896c3c https://doi.org/10.1149/1.2409002 Zobrazit plný text záznamu