N-nitrosodimethylamine formation during oxidation of N,N-dimethylhydrazine compounds by peroxymonosulfate: Kinetics, reactive species, mechanism and influencing factors

Autor:	Linlu, Shen, Zhonglin, Chen, Jing, Kang, Pengwei, Yan, Jimin, Shen, Binyuan, Wang, Shengxin, Zhao, Lanbo, Bi, Shuyu, Wang, Yizhen, Cheng
Rok vydání:	2022
Předmět:	Dimethylhydrazines Kinetics Environmental Engineering Health Toxicology and Mutagenesis Humans Environmental Chemistry Oxidation-Reduction Pollution Waste Management and Disposal Water Pollutants Chemical Dimethylnitrosamine Peroxides
Zdroj:	Journal of Hazardous Materials. 428:128191
ISSN:	0304-3894
DOI:	10.1016/j.jhazmat.2021.128191
Popis:	This study found that peroxymonosulfate (PMS) oxidation without activation has the potential to generate a suspected human carcinogen, N-nitrosodimethylamine (NDMA), in water containing N,N-dimethylhydrazine compounds. Considerable amounts of NDMA formed from three compounds by PMS oxidation were observed. 1,1,1',1'-Tetramethyl-4,4'-(methylene-di-p-phenylene) disemicarbazide (TMDS), which is an industrial antiyellowing agent and light stabilizer, was used as a representative to elucidate the kinetics, transformation products, mechanism and NDMA formation pathways of PMS oxidation. TMDS degradation and NDMA formation involved direct PMS oxidation and singlet oxygen (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fa6930ca7c7cd51487747b2e906df655 https://doi.org/10.1016/j.jhazmat.2021.128191 Zobrazit plný text záznamu Full Text from ScienceDirect