Dichotomous Reaction Pathways for the Oxidative Palladium(II)-Catalyzed Intramolecular Acyloxylation of Alkenes
| Autor: | Mélanie M. Lorion, Giovanni Poli, Julie Oble, Fadila Louafi |
|---|---|
| Přispěvatelé: | Institut Parisien de Chimie Moléculaire (IPCM), Institut de Chimie du CNRS (INC)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Centre National de la Recherche Scientifique (CNRS), CNRS, UPMC, Labex Michem, CMST COST Action (CARISMA) [CM1205], Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Allylic rearrangement Olefin fiber palladium(II) alkenoic acids Stereochemistry 010405 organic chemistry Carboxylic acid Organic Chemistry chemistry.chemical_element food and beverages 010402 general chemistry Medicinal chemistry 01 natural sciences Catalysis 0104 chemical sciences reaction mechanisms chemistry Intramolecular force oxypalladation Moiety [CHIM]Chemical Sciences C-H activation Amination Palladium |
| Zdroj: | SYNLETT SYNLETT, Georg Thieme Verlag, 2015, 26 (16), pp.2237-2242. ⟨10.1055/s-0035-1560071⟩ SYNLETT, 2015, 26 (16), pp.2237-2242. ⟨10.1055/s-0035-1560071⟩ |
| ISSN: | 0936-5214 1437-2096 |
| DOI: | 10.1055/s-0035-1560071⟩ |
| Popis: | International audience; This work provides an in-depth investigation of the Pd(II)-catalyzed oxidative cyclization of various alkenoic acids bearing different tethers between the carboxylic acid moiety and the olefin function, showcasing how different mechanistic pathways (oxypalladation or allylic C–H activation) can be operative. The factors biasing toward one or the other of these reactivities are rationally discussed and compared with our recent studies on the Pd(II)-catalyzed intramolecular amination. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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