Gold(l)-catalyzed formation of furans by a Claisen type rearrangement of ynenyl allyl ethers
| Autor: | Fabien Gagosz, Florin M. Istrate |
|---|---|
| Přispěvatelé: | Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: |
Letter
010405 organic chemistry Chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Claisen rearrangement Organic Chemistry furans quaternary centers 010402 general chemistry 01 natural sciences Medicinal chemistry Carroll rearrangement 0104 chemical sciences Catalysis lcsh:QD241-441 lcsh:Organic chemistry Organic chemistry lcsh:Q gold-catalysis lcsh:Science |
| Zdroj: | Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2011, 7, pp.878-885. ⟨10.3762/bjoc.7.100⟩ Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 878-885 (2011) |
| ISSN: | 1860-5397 |
| DOI: | 10.3762/bjoc.7.100⟩ |
| Popis: | International audience; A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions. © 2011 Istrate and Gagosz. |
| Databáze: | OpenAIRE |
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