Secondary Oxide Phosphines to Promote Tandem Acyl-Alkyl Coupling/Hydrogen Transfer to Afford (Hydroxyalkyl)rhodium Complexes. Theoretical and Experimental Studies
| Autor: | Antonio Rodríguez-Diéguez, José M. Seco, Virginia San Nacianceno, Antonio J. Mota, Lourdes Ibarlucea, Claudio Mendicute-Fierro, María A. Garralda |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Tandem 010405 organic chemistry Dimer Oxide chemistry.chemical_element Hydrogen transfer 010402 general chemistry Diphenylphosphine oxide 01 natural sciences Medicinal chemistry 0104 chemical sciences Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Isoquinoline Alkyl |
| Zdroj: | Inorganic chemistry. 57(9) |
| ISSN: | 1520-510X |
| Popis: | Acyl(σ-norbornenyl)rhodium(III) dimer [Rh(μ-Cl)(C9H6NCO)(C7H9)L]2 (1) (C7H9 = σ-norbornenyl; L = 4-picoline, isoquinoline) reacts with diphenylphosphine oxide (SPO) to undergo a one-pot reaction in... |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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