Copper-Catalyzed Enantioselective Hydrosilylation of Allenes to Access Axially Chiral (Cyclohexylidene)ethyl Silanes

Autor:	Shu Li, Jian-Lin Xu, Yun-He Xu
Rok vydání:	2022
Předmět:	Organic Chemistry Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic Letters. 24:6054-6059
ISSN:	1523-7052 1523-7060
DOI:	10.1021/acs.orglett.2c02359
Popis:	A novel strategy of copper-catalyzed regio- and enantioselective hydrosilylation of 4-substituted vinylidenecyclohexanes with silanes was developed. In this protocol, various allenes and silanes were used to afford the corresponding (cyclohexylidene)ethyl silanes in moderate to high yields with good enantioselectivities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f8d8cf2829989ecf19cbd5b70008bf25 https://doi.org/10.1021/acs.orglett.2c02359 Zobrazit plný text záznamu