Autor:	Kaushalendra Patel, Veeranjaneyulu Lanke, Ilan Marek
Rok vydání:	2022
Předmět:	Colloid and Surface Chemistry Molecular Structure Stereoisomerism General Chemistry Biochemistry Carbon Catalysis
Zdroj:	Journal of the American Chemical Society. 144(16)
ISSN:	1520-5126
Popis:	Organoaluminum species promote a smooth nucleophilic substitution at the quaternary carbon stereocenter of stereodefined polysubstituted cyclopropyl methyl phosphate with a complete inversion of configuration, even when more reactive functional groups are present. The regio- and diastereoselectivity of the substitution is attributed to the existence of a bicyclobutonium intermediate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f89a926087189483fc455c53125f0a12 https://pubmed.ncbi.nlm.nih.gov/35412821 Zobrazit plný text záznamu