Dibromo{N-[2-(diphenylphosphino)benzylidene]-2,6-diisopropylaniline-κ2N,P}nickel

Autor:	Carlos A. L. Filgueiras, James L. Wardell, R.A. Howie, Cláudio M. Ziglio, Geraldo L. Crossetti
Rok vydání:	2001
Předmět:	chemistry.chemical_classification Aldimine Stereochemistry Ligand chemistry.chemical_element General Medicine Crystal structure Bite angle Medicinal chemistry General Biochemistry Genetics and Molecular Biology Nickel chemistry.chemical_compound Aniline chemistry Molecule Chelation
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 57:1279-1281
ISSN:	0108-2701
Popis:	In the title compound, [NiBr(2)(C(31)H(32)NP)], (I), the second reported example of a nickel-iminophosphine N,P-chelate in which the Ni atom has tetrahedral coordination, the Ni coordination is distorted as a consequence of the N-Ni-P chelate bite angle of 91.07 (6) degrees compensated by the Br-Ni-Br angle of 126.385 (18) degrees. In (I) and its analogue, viz. dichloro[[2-(4-isobutyloxazol-2-yl)phenyl]diphenylphosphine-N,P]nickel(II), the Ni-N and Ni-P distances are greater and the N-Ni-P ligand bite angles smaller than those observed in a series of related complexes with square-planar nickel.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f8765337ce0e09f395530835ce6fe392 https://doi.org/10.1107/s0108270101013907 Zobrazit plný text záznamu Plný text