| Autor: |
Richard J. Curry, A. A. Damitha T. Adikaari, Mathieu Berard, Anthony K. Cheetham, S. Ravi P. Silva, Paul Henri Guering, Isabelle Etchart |
| Jazyk: |
angličtina |
| Rok vydání: |
2012 |
| Předmět: |
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| Popis: |
The first detailed study that combines the use of a new generation of high-efficiency Yb3+:Ho3+ co-doped Y2BaZnO5 near-infrared up-converting phosphors with organic photovoltaic devices is reported. We show that it is possible to obtain a Jsc of 16 µA / cm2 under 986 nm illumination (~390 mW / cm2 corresponding to ~37 suns) leading to an up-conversion external quantum efficiency (UC EQE) of 0.0052%. Through modification of the organic photovoltaic devices to incorporate transparent electrodes we show that UC EQE could be increased to 0.031 %, matching that achieved in amorphous-Si:H PV cells. Accounting for the full spectral range that may be absorbed by the phosphor(~870–1030 nm) yields an up-conversion power conversion efficiency (UC PCE) of 0.073% which again could be improved to 0.45% using transparent electrodes. This technique for utilizing the near-infrared spectral region may therefore offer a potential route to improving the performance of organic photovoltaic devices as research into discovering high-efficiency up-converting phosphors continues to provide improved materials. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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