Multivariate zeolitic imidazolate frameworks with an inverting trend in flexibility

Autor:	Arijit Halder, Ryan A. Klein, Rachel Lively, C. Michael McGuirk
Rok vydání:	2022
Předmět:	Materials Chemistry Metals and Alloys Ceramics and Composites Imidazoles Zeolites General Chemistry Adsorption Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications (Cambridge, England). 58(81)
ISSN:	1364-548X
Popis:	Through systematic linker substitution in a flexible zeolitic imidazolate framework (ZIF) with step-shaped adsorption-desorption, structural intermediates between the known open and closed phases were isolated. Reflecting this, modulative sorption behaviour with an inverting adsorption pressure trend-in which the step pressure decreases and then increases again with increasing mixed linker concentration-is observed, highlighting how linker substitution modifies the energetic landscape of framework flexibility.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f80ccb0009bffdd609fafed90a71756d https://pubmed.ncbi.nlm.nih.gov/36134482 Zobrazit plný text záznamu