Predicting Rearrangement-Competent Terpenoid Oxidation Levels

Autor:	Dean J. Tantillo, Christina H. McCulley
Rok vydání:	2020
Předmět:	Models Molecular Thesaurus (information retrieval) Chemistry General Chemistry Computational biology Biochemistry Catalysis Terpenoid Biosynthetic Pathways Colloid and Surface Chemistry Models Chemical Density functional theory Oxidation-Reduction Sesquiterpenes Density Functional Theory
Zdroj:	Journal of the American Chemical Society. 142:6060-6065
ISSN:	1520-5126 0002-7863
DOI:	10.1021/jacs.9b12398
Popis:	Results of density functional theory calculations on rearrangements of potential biosynthetic precursors to the sesquiterpenoid illisimonin A reveal that only some possible precursors, those with certain specific oxidation patterns, are rearrangement-competent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f807b72b8ce1d552bb42d6be8345a878 https://doi.org/10.1021/jacs.9b12398 Zobrazit plný text záznamu