Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

Autor:	Susumu Sato, Yoshiyasu Kaimori, Kenta Suzuki, Seiya Shimada, Tsuneomi Kawasaki, Arimasa Matsumoto, Natsuki Hara, Toru Asahi, Kenso Soai
Rok vydání:	2021
Předmět:	Materials science organic chemicals Metals and Alloys nutritional and metabolic diseases Soai reaction General Chemistry Polarization (waves) Ferroelectric crystal Catalysis Triglycine sulfate Surfaces Coatings and Films Electronic Optical and Magnetic Materials Autocatalysis chemistry.chemical_compound chemistry Chemical physics Electric field polycyclic compounds Materials Chemistry Ceramics and Composites lipids (amino acids peptides and proteins) heterocyclic compounds Enantiomeric excess Chirality (chemistry)
Zdroj:	Chemical communications (Cambridge, England). 57(49)
ISSN:	1364-548X
Popis:	Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f7a4fc6e0cbb03a564d02bb73c1e461f https://pubmed.ncbi.nlm.nih.gov/34023863 Zobrazit plný text záznamu