Straightforward synthesis of α,β-epoxysilanes from terminal epoxides by lithium 2,2,6,6-tetramethylpiperidide-mediated deprotonation-in situ silylation

Autor:	David M. Hodgson, Steven J. Coote, Nigel J. Reynolds
Rok vydání:	2002
Předmět:	In situ Trimethylsilyl chloride Silylation Organic Chemistry chemistry.chemical_element General Medicine Biochemistry Combinatorial chemistry chemistry.chemical_compound Deprotonation chemistry Drug Discovery Organic chemistry Lithium
Zdroj:	Tetrahedron Letters. 43:7895-7897
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(02)01893-2
Popis:	Lithiation-in situ silylation of simple terminal epoxides using lithium 2,2,6,6-tetramethylpiperidide in combination with trimethylsilyl chloride provides a direct and experimentally convenient process for the synthesis of trans-α,β-epoxysilanes. © 2002 Elsevier Science Ltd. All rights reserved.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f7211e0722d70d9088ba00226e5a73ac https://doi.org/10.1016/s0040-4039(02)01893-2 Zobrazit plný text záznamu Full Text from ScienceDirect