A Molecular Conductor Based on Axially CN-Substituted Cobalt Tetrabenzoporphyrin

Autor:	Naho Muramoto, Masaki Matsuda, Hiroko Ohishi, Madoka Tofuku, Jun-ichi Yamaura
Rok vydání:	2011
Předmět:	459.92 chemistry.chemical_compound chemistry Phthalocyanine chemistry.chemical_element Physical chemistry General Chemistry Crystal structure Axial symmetry Cobalt Conductor
Zdroj:	Chemistry Letters. 40:1257-1259
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.2011.1257
Popis:	A molecular conductor based on axially CN-substituted cobalt tetrabenzoporphyrin is reported. The crystal structure is isomorphous with a phthalocyanine-based conductor, however, estimation of effectiveness of π–π overlap and electrical transport measurement reveal that a slight change in molecular structure of macrocyclic π-conjugated ligands has significant influence on intermolecular interaction and electrical properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6f24f1f44b77dbe48401856df0b9e3c https://doi.org/10.1246/cl.2011.1257 Zobrazit plný text záznamu