Optimization of fluoride removal by Al doped ZnO nanoparticles using response surface methodology from groundwater
Autor: | Mohammad Khalid, Parwathi Pillai, Swapnil Dharaskar |
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Rok vydání: | 2021 |
Předmět: |
Environmental Engineering
Materials science Central composite design Health Toxicology and Mutagenesis 0208 environmental biotechnology 02 engineering and technology 010501 environmental sciences 01 natural sciences Ion Water Purification chemistry.chemical_compound Fluorides Adsorption Environmental Chemistry Response surface methodology Fourier transform infrared spectroscopy Groundwater 0105 earth and related environmental sciences Doping Public Health Environmental and Occupational Health General Medicine General Chemistry Pollution 020801 environmental engineering Kinetics chemistry Chemical engineering Particle-size distribution Zinc Oxide Fluoride Water Pollutants Chemical |
Zdroj: | Chemosphere. 284 |
ISSN: | 1879-1298 |
Popis: | The current novel work presents the optimization of factors affecting defluoridation by Al doped ZnO nanoparticles using response surface methodology (RSM). Al doped ZnO nanoparticles were synthesized by the sol-gel method and validated by FTIR, XRD, TEM/EDS, TGA, BET, and particle size analysis. Moreover, a central composite design (CCD) was developed for the experimental study to know the interaction between Al doped ZnO adsorbent dosage, initial concentration of fluoride, and contact time on fluoride removal efficiency (response) and optimization of the process. Analysis of variance (ANOVA) was achieved to discover the importance of the individual and the effect of variables on the response. The model predicted that the response significantly correlated with the experimental response (R2 = 0.97). Among the factors, the effect of adsorbent dose and contact time was considered to have more influence on the response than the concentration. The optimized process parameters by RSM presented the adsorbent dosage: 0.005 g, initial concentration of fluoride: 1.5 g/L, and contact time: 5 min, respectively. Kinetic, isotherm, and thermodynamic studies were also investigated. The co-existing ions were also studied. These results demonstrated that Al doped ZnO could be a promising adsorbent for effective defluoridation for water. |
Databáze: | OpenAIRE |
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