Penta­carbonyl-2κ5 C-chlorido-1κCl-bis­[1(η5)-cyclo­penta­dien­yl](μ-α-oxido­benzyl­idene-1:2κ2 O:C)titanium(IV)tungsten(0)

Autor:	I.B.J. Nel, Matthias W. Esterhuysen, Catharine Esterhuysen, Stephanie Cronje
Jazyk:	angličtina
Rok vydání:	2008
Předmět:	Metal-Organic Papers Chemistry chemistry.chemical_element General Chemistry Tungsten Condensed Matter Physics Ring (chemistry) Chloride Medicinal chemistry Metal visual_art medicine visual_art.visual_art_medium General Materials Science medicine.drug Titanium
Zdroj:	Acta Crystallographica Section E: Structure Reports
ISSN:	1600-5368
Popis:	The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6d3a9722a7c8d5464d5410f500ff8c2 http://europepmc.org/articles/PMC2960115 Zobrazit plný text záznamu