1H- and 13C-n.m.r. assignments for structural elements of xylose-containing N-linked oligosaccharides, using 1D- and 2D-n.m.r. experiments
| Autor: | Johannis P. Kamerling, Jan B. Bouwstra, Johannes F.G. Vliegenthart, János Kerékgyártó |
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| Rok vydání: | 1989 |
| Předmět: |
Carbon Isotopes
Magnetic Resonance Spectroscopy Xylose Aqueous solution Stereochemistry Chemistry Molecular Sequence Data Organic Chemistry Oligosaccharides Pulse sequence General Medicine Nuclear magnetic resonance spectroscopy Biochemistry Analytical Chemistry chemistry.chemical_compound Carbohydrate Sequence Carbohydrate chains Carbohydrate Conformation Spectroscopy Hydrogen |
| Zdroj: | Carbohydrate Research. 186:39-49 |
| ISSN: | 0008-6215 |
| DOI: | 10.1016/0008-6215(89)84003-0 |
| Popis: | 1H-N.m.r. and 13C-n.m.r. spectral assignments for synthetic beta-D-Xyl-(1----2)-beta-D-Man-OMe, beta-D-Xyl-(1----2)-[alpha-D-Man-(1----3)]-beta-D-Man-OMe, beta-D-Xyl-(1----2)-[alpha-D-Man-(1----6)]-beta-D-Man-OMe, and beta-D-Xyl-(1----2)-[alpha-D-Man-(1----3)]-[alpha-D-Man-(1----6)]- beta-D-Man-OMe, which are structural elements of xylose-containing carbohydrate chains from N-glycoproteins, have been made on the basis of 1D and 2D (DQF 1H-1H COSY, HOHAHA) 500-MHz 1H-n.m.r. spectroscopy and 1D 50-MHz 13C-n.m.r. spectroscopy, respectively. |
| Databáze: | OpenAIRE |
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