Photochemical intermediates of trans-Rh(CO)L2Cl where L=PMe3, PBu3, and i-Pr2HN and cis-Rh(CO)2(i-Pr2HN)Cl in frozen organic glasses
| Autor: | J. Timothy Bays, James A. Franz, W.Bruce Scallorn, Callie A Weiss, Rinaldo Poli, John C. Linehan, Thomas E. Bitterwolf |
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| Přispěvatelé: | University of Idaho [Moscow, USA], PACIFIC NORTHWEST NATIONAL LABORATORY RICHLAND USA, Partenaires IRSTEA, Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA)-Institut national de recherche en sciences et technologies pour l'environnement et l'agriculture (IRSTEA), Laboratoire de Synthèse et Electrosynthèse Organométalliques (LSEO), Centre National de la Recherche Scientifique (CNRS)-Université de Bourgogne (UB) |
| Rok vydání: | 2002 |
| Předmět: |
Photolysis
010405 organic chemistry Chemistry Annealing (metallurgy) Organic Chemistry Photodissociation Amine derivatives 010402 general chemistry Photochemistry Glass matrix 01 natural sciences Biochemistry 0104 chemical sciences Inorganic Chemistry DFT analysis chemistry.chemical_compound Nujol Excited state Materials Chemistry [CHIM.COOR]Chemical Sciences/Coordination chemistry Physical and Theoretical Chemistry Phosphine |
| Zdroj: | Journal of Organometallic Chemistry Journal of Organometallic Chemistry, Elsevier, 2002, 652 (1-2), pp.95-104. ⟨10.1016/S0022-328X(02)01312-8⟩ |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(02)01312-8 |
| Popis: | International audience; The Nujol glass matrix photolyses of Rh(CO)(PMe3)2Cl (1), Rh(CO)(PBu3)2Cl (2), Rh(CO)2(i-Pr2HN)Cl (3), and Rh(CO)(i-Pr2HN)2Cl (4), have been examined. Phototolysis of 1 (λirr>400 nm) and 2 (350 |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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