Addition of [(η5-C5Me5)IrH4] to a zwitterionic silylene: stepwise formation of iridium(v)-silyl and iridium(iii)-silylene complexes

Autor:	Matthias Driess, Thomas Braun, Anna Penner, Carsten Präsang, Ann-Katrin Jungton, Antje Meltzer
Rok vydání:	2010
Předmět:	Inorganic Chemistry chemistry.chemical_compound chemistry Silylation Ligand Hydride Silylene Moiety chemistry.chemical_element Iridium Photochemistry Medicinal chemistry
Zdroj:	Dalton Transactions. 39:5436
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c0dt00236d
Popis:	The first zwitterionic silyl-iridium(v) complex is generated by insertion of silylene into an iridium-hydrogen bond of the iridium(v) hydride , [(eta(5)-C(5)Me(5))IrH(4)]. Complex undergoes proton migration from an IrH moiety to the terminal CH(2) group of the silyl ligand to furnish the N-donor stabilised Ir(iii)-silylene complex .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f695478d37bc34220b427a10ab9ddfc0 https://doi.org/10.1039/c0dt00236d Zobrazit plný text záznamu