Intermolecular interaction effects on second hyperpolarizabilities of clusters including charged species
| Autor: | Ryohei Kishi, Nozomi Nakagawa, Hideaki Takahashi, Masayoshi Nakano, Shin-ichi Furukawa, Suguru Ohta |
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| Rok vydání: | 2006 |
| Předmět: | |
| Zdroj: | Scopus-Elsevier |
| ISSN: | 1875-8983 1472-7978 |
| DOI: | 10.3233/jcm-2006-61-417 |
| Popis: | We investigate the intermolecular-interaction effects on the longitudinal second hyperpolarizabilities (γ) for two types of π−π stacking clusters: C$_{5}$H$_{7}^{p}$ dimer and π-conjugated main chains (C$_{n}$H$_{np2}$, 6 l n l 16) interacting in both end regions with two allyl cations (C$_{3}$H$_{5}^{p})$. The γ values are calculated by the finite-field approach using several ab initio molecular orbital and density functional methods. It is found that in the first model the π− π interaction between the upper and lower π-orbitals significantly reduces the magnitude of effective γ per monomer, while the second model exhibits a remarkable enhancement of γ values as compared to those of isolated main chains. The analysis using the hyperpolarizability density and orbital interaction elucidates that the reduction of longitudinal γ value in the first model originates in the reduction of longitudinal π-conjugated electron distributions due to the perpendicular π−π orbital interactions, whereas the enhancement of longitudinal γ in the second model is caused by the intermolecular charge transfer between both end perturbing molecules via the main chain. On the basis of these results, we discuss a novel guideline of controlling third-order nonlinear optical properties of clusters. |
| Databáze: | OpenAIRE |
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