TpPt(IV)Me(H)2 Forms a σ-CH4 Complex That Is Kinetically Resistant to Methane Liberation

Autor:	Ariel Haskel, H. Christine Lo, Ehud Keinan, Moshe Kapon
Rok vydání:	2002
Předmět:	Reaction mechanism Chemistry Inorganic chemistry General Chemistry Biochemistry Medicinal chemistry Catalysis Methane Reductive elimination chemistry.chemical_compound Colloid and Surface Chemistry Kinetic isotope effect Chemical reduction Liberation Methanol
Zdroj:	Journal of the American Chemical Society. 124:3226-3228
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja010464c
Popis:	Complex 1 undergoes H/D scrambling in methanol without concomitant liberation of either methane or dihydrogen (k(H)/k(D) = 0.76, 55 degrees C). The measured isotope effect was proposed to directly relate to the initial reductive coupling step in reductive elimination reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f64840e67e8dd3daccaae2e003051b0b https://doi.org/10.1021/ja010464c Zobrazit plný text záznamu