Beta-D-glucopyranosyl caldarchaetidylglycerol is the main lipid of the acidophilic, mesophilic, ferrous iron-oxidising archaeon Ferroplasma acidiphilum
Autor: | G. I. Karavaiko, Tatiana A. Pivovarova, Stanislav E. Esipov, Stanislav G. Batrakov, Vladimir I Sheichenko |
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Rok vydání: | 2002 |
Předmět: |
Chromatography
Magnetic Resonance Spectroscopy biology Spectrophotometry Infrared Chemistry Ferroplasma acidiphilum Silica gel Infrared spectroscopy Glyceryl Ethers Thermoplasmales Cell Biology Mass spectrometry biology.organism_classification Ferrous Matrix-assisted laser desorption/ionization chemistry.chemical_compound Column chromatography Spectrometry Mass Matrix-Assisted Laser Desorption-Ionization Ferrous Compounds Glycolipids Molecular Biology Oxidation-Reduction Chemical decomposition Pyrans |
Zdroj: | Biochimica et biophysica acta. 1581(1-2) |
ISSN: | 0006-3002 |
Popis: | Chloroform-methanol-extractable lipids account for about 5% by weight of dry cells of the acidophilic, autotrophic, mesophilic, ferrous compound-oxidising, cell wall-less archaeon Ferroplasma acidiphilum strain Y(T), about 90% of these being contributed by phospholipids and glycophospholipids. The most abundant constituent (about 55% of total lipids) was purified by DEAE cellulose and silica gel column chromatography. By means of matrix-assisted laser desorption ionisation mass spectrometry, infrared spectroscopy, (1)H-nuclear magnetic resonance spectroscopy, and chemical degradation experiments it was established to be beta-D-glucopyranosyl caldarchaetidylglycerol, the isopranyl chains of which have a cyclopentane ring each. |
Databáze: | OpenAIRE |
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