A Novel Approach to C-Trimethylsilyl-1,3-azoles

Autor: Andrej A. Tolmachev, Aleksandr A. Yurchenko, Anatolij S. Merkulov, Evgenij V. Zarudnitskii, Igor I. Pervak, Aleksandr M. Pinchuk
Rok vydání: 2006
Předmět:
Zdroj: ChemInform. 37
ISSN: 1522-2667
0931-7597
Popis: Direct silylation of 1,3-azoles with bromotrimethylsilane in the presence of triethylamine was investigated. 5-Phenyloxazole, benzoxazole, 1-methyl-1,2,4-triazole, 2-aryl-1,3,4-oxa- and thiadiazoles were found to give the corresponding 2- or 5-trimethylsilyl derivatives.
Databáze: OpenAIRE