Novel multidentate sulfur-nitrogen ligands with enhanced complexation properties
| Autor: | Ella Kriemen, Dietmar Stalke, Margret M. Meinholz, Maika Klemmer |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
Denticity Trimethylsilyl 010405 organic chemistry Stereochemistry Ligand Organic Chemistry chemistry.chemical_element General Chemistry 010402 general chemistry Alkali metal 01 natural sciences Nitrogen Medicinal chemistry Sulfur Catalysis 3. Good health 0104 chemical sciences Coordination complex Sulfur diimide chemistry.chemical_compound chemistry |
| Zdroj: | Chemistry (Weinheim an der Bergstrasse, Germany). 17(34) |
| ISSN: | 1521-3765 |
| Popis: | Di(tert-butyl)sulfur diimide and bis(trimethylsilyl)sulfur diimide were reacted with different metalated amines to form versatile novel multidentate ligand systems with side-arm donation. Their complexation properties in terms of ligand design, denticity and the cation size are discussed. We report herein the synthesis and structure elucidation of [(tBuN)(2)S{LiMe(2)N(C(6)H(4))S(NtBu)(2)}(2)] (1), [(Li{Me(2)N(C(6)H(4))S(NSiMe(3))(2)})(2)] (2), [(Li(thf){Me(2)N(C(6)H(4))S(NSiMe(3))(2)})(2)] (3), [(Li{2-PicS(NSiMe(3))(2)})(2)] (4), [(Li{Me(2)N(CH(2))(2)N(Me)S(NSiMe(3))(2)})(2)] (5), [(Na{Me(2)N(CH(2))(2)N(Me)S(NSiMe(3))(2)})(2)] (6) and [(K{Me(2)N(C(6)H(4))S(NSiMe(3))(2)})(2)] (7). |
| Databáze: | OpenAIRE |
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