Bispyranopyrazoles as Green Corrosion Inhibitors for Mild Steel in Hydrochloric Acid: Experimental and Theoretical Approach
Autor: | Gurmeet Singh, Jiyaul Haque, Mumtaz A. Quraishi, Priyanka Singh, Madhan Kumar |
---|---|
Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: |
Materials science
General Chemical Engineering Hydrochloric acid 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Article Electrochemical corrosion 0104 chemical sciences Corrosion lcsh:Chemistry chemistry.chemical_compound Adsorption chemistry lcsh:QD1-999 Chemisorption Molecule Density functional theory 0210 nano-technology Volume concentration Nuclear chemistry |
Zdroj: | ACS Omega, Vol 3, Iss 9, Pp 11151-11162 (2018) ACS Omega |
ISSN: | 2470-1343 |
Popis: | In the present study, we have synthesized two novel corrosion inhibitors BP-1 and BP-2 and evaluated their corrosion inhibition property on mild steel (MS) in acid solution through weight loss and electrochemical corrosion techniques. The corrosion test results reveal that both compounds inhibit corrosion by an adsorption mechanism and display inhibition efficiency more than 95% at a low concentration of 1.72 × 10–4 M. From the surface analysis of the protective film on MS, it was corroborated that adsorption of inhibitor molecules occurred on the MS surface through chemisorption, which further suppresses the corrosion rate. Density functional theory simulated data helps correlate the experimental trend with the theoretical study. |
Databáze: | OpenAIRE |
Externí odkaz: |