De Novo Synthesis of Phenols and Naphthols through Oxidative Cycloaromatization of Dienynes
Autor: | Hong-Fa Wang, Weiwei Zi, Tian-Zhu Qin, Ming-Guang Rong, Xin-Rui Liu |
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Rok vydání: | 2018 |
Předmět: | |
Zdroj: | Organic Letters. 20:6289-6293 |
ISSN: | 1523-7052 1523-7060 |
Popis: | In this work, a rhodium-catalyzed oxidative cycloaromatization of dienynes, which provides a highly straightforward and efficient way to access polysubstituted naphthols and phenols under mild conditions, is described. Challenged electron-withdrawing groups are well tolerated in this protocol, and late-stage phenyl ring formation is demonstrated. |
Databáze: | OpenAIRE |
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