Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR
| Autor: | Edward J. King, Thomas H. West, Andrew G. Leach, Ariana B. Jones, Marc Reid, Craig P. Johnston, Ruth E. Dooley, Guy C. Lloyd-Jones |
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| Přispěvatelé: | University of St Andrews. School of Chemistry |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
RM
Order of reaction Ketone NDAS Protonation 010402 general chemistry 01 natural sciences Biochemistry Medicinal chemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry QD R2C Carbanion chemistry.chemical_classification 010405 organic chemistry General Chemistry Silyl enol ether QD Chemistry Enol 0104 chemical sciences chemistry Reagent Alkoxide BDC |
| Zdroj: | Johnston, C, West, T, Dooley, R, Reid, M, Jones, A B, King, E, Leach, A G & Lloyd-jones, G C 2018, ' Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR ', Journal of the American Chemical Society . https://doi.org/10.1021/jacs.8b06777 Johnston, C P, West, T H, Dooley, R E, Reid, M, Jones, A B, King, E J, Leach, A G & Lloyd-Jones, G C 2018, ' Anion-Initiated Trifluoromethylation by TMSCF3: Deconvolution of the Siliconate-Carbanion Dichotomy by Stopped-Flow NMR/IR ', Journal of the American Chemical Society, vol. 140, no. 35, pp. 11112-11124 . https://doi.org/10.1021/jacs.8b06777 |
| ISSN: | 0002-7863 |
| Popis: | The research leading to these results has received funding from the European Research Council under the European Union’s Seventh Framework Programme (FP7/2007–2013)/ERC grant agreement no. 340163. The Carnegie Trust provided a collaborative research grant. C.P.J. thanks the EC for an International Outgoing Fellowship (PIOF-GA-2013-627695). The mechanism of CF3 transfer from R3SiCF3 (R = Me, Et, iPr) to ketones and aldehydes, initiated by M+X– ( |
| Databáze: | OpenAIRE |
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